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where kf and kb are the rate constants (cm s 1) at potential E, kf0 and kb0 are the rate constants (cm s 1) at E = 0, a is the transfer coefficient (0 < a < 1) 1), and C0 Ox and C0 are the concentrations (mol cm 3) of Ox and Red at the electrode surRed face. Equations (5.2) and (5.3) show that kf and kb depend on the electrode potential and the value of a. Thus, vf and vb also depend on the electrode potential and a as shown in Fig. 5.2. It should be noted that, in some potential regions, the oxidation and reduction processes occur simultaneously. However, the net reaction is a reduction if vf > vb and an oxidation if vf < vb. When vf = vb, the electrode reaction is in equilibrium and no change occurs overall. The potential at which the reaction is in equilibrium is the equilibrium potential. If we express it by Eeq (V), we get the following Nernst equation from Eqs (5.2) and (5.3): Eeq E 0H RT COx ln nF CRed .net barcode reader code Using Barcode Reader In VB . NET | Free Source Code & Tutorials
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